Production of Free Radicals from Adamantane by High Energy Irradiation

نویسندگان

  • W. G. FILBY
  • K. GÜNTHER
چکیده

The nature and properties of radicals produced by the action of electron and ^-radiation on adamantane have been investigated. Radicals produced by irradiation at 77 °K are stable to around room temperature, while irradiation at the latter temperature yields well resolved spectra of species stable to about 130 °C. The significance of the latter, assigned as the 1-adamantyl radical, in the formation of trapped radicals is discussed.

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تاریخ انتشار 2012